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Ti4+-mixed FePO4·xH2O precursor was prepared by co-precipitation method, for which Ti4+ cations were added in the process of preparing FePO4·xH2O to pursue a effective and homogenous doping way.Ti4+-doped LiFePO4 was prepared by an ambient-reduction and post-sintering method using the as-prepared precursor, Li2CO3 and oxalic acid as raw materials.