分子铁磁体是指使用制备分子化合物的常规方法合成出具有磁铁一样性质的、主要由分子组装的物质,使其在某临界温度(Tc)下具有自发的磁化作用。如1986年美国杜邦公司的Ailler率先报道了Tc=4.8 K的配合物型分子铁磁体。分子铁磁体的出现使以往仅以金属或离子晶格组成的磁性材料有可能以分子集合的方式,在通常条件下的溶液化学中实现,这种研究方式的改变以及分子基块合成方式的无限性和分子结合形式的多样性 Molecular ferromagnetism refers to the use of conventional methods for the preparation of molecular compounds to synthesize magnetically-identical, predominantly molecularly-assembled species that spontaneously magnetize at a critical temperature (Tc). For example, Ailler of DuPont in 1986 first reported the complex-type molecular ferromagnet with Tc = 4.8 K. The advent of molecular ferromagnets has made it possible to use magnetic materials composed of only metallic or ionic lattices in the form of molecular assemblies in solution chemistry under normal conditions. Such changes in the research methods and the infinite The diversity of sexual and molecular combinations