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Ionothermal synthesis was used to prepare a novel amino acid containing hybrid zincophosphate monomer,[Zn(HPO4)(H2PO4)][C6H10N3O2](denoted as ZnPO-CJ58).The inorganic framework of [Zn(HPO4)(H2PO4)]·[C6H10N3O2] consists of 4-membered rings formed by Z