对叔丁基杯[4]芳烃-1,3-二醛基衍生物1与水杨酰肼、烟酰肼、异烟酰肼反应,合成了具有开链结构新型杯[4]多重氮杂衍生物2a～2c,产率分别为88%,85%和90%.化合物1与乙二酰肼、丙二酰肼、己二酰肼反应,得到具有桥联结构的新型杯[4]多重氮杂衍生物3a～3c,产率分别为86%,89%和90%.新化合物的结构经元素分析、质谱、核磁共振谱等表征证实,杯[4]芳烃单元均为1,3-取代且采取锥式构象. The reaction of p-tert-butylcalix [4] arene-1,3-dialdehyde derivative 1 with salicylic hydrazide, nicotinic acid hydrazide and isonicotinic acid hydrazide gave novel cup [4] polyazepine derivatives with open-chain structure 2a ~ 2c, the yields were 88%, 85% and 90%, respectively.Compound 1 reacted with oxalic hydrazide, malonic acid hydrazide and adipic acid hydrazide to obtain novel cup [4] The yields of 3a ~ 3c were 86%, 89% and 90%, respectively.The structures of the new compounds were confirmed by elemental analysis, MS and NMR spectra to confirm that the calix [4] Take conical conformation.