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将Leibler,Whitmore和Mayes等近期关于非晶嵌段共聚物“稀固体溶液”的理论应用于嵌段聚共聚物结晶型“稀固体溶液”结晶行为的研究。发现球状共聚物胶束既可起成核剂作用,也可起抑制成核作用。报导了当共聚物胶束由球形变为非球形时,共聚物胶束的上述作用都会发生较大的变化,并根据Leibler和Mayes分别提出的球形和非球形胶束理论解释了这一实验现象。
Recently, Leibler, Whitmore and Mayes et al. Applied the theory of “dilute solid solution” of amorphous block copolymer to study the crystallization behavior of “dilute solid solution” of block copolymer. It was found that the spherical copolymer micelles can act as both a nucleator and a nucleator. Reported that when the copolymer micelles change from spherical to non-spherical shape, the above-mentioned effects of the copolymer micelles will be greatly changed, and this experimental phenomenon is explained according to the spherical and non-spherical micellar theories respectively proposed by Leibler and Mayes .