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The title complex CoL(H2O)32·H2O(C26H46N4O21S4Co2),where L = taurine-5-methyl-2-hydroxyisophthalaldehydes,has been synthesized and characterized by IR and X-ray diffraction analysis.The crystal of the complex belongs to the triclinic system,space group P1,with a = 11.197(4),b = 13.309(5),c = 14.486(5),α = 78.827(13),β = 70.547(11),γ = 81.058(13)°,Mr = 996.77,S = 1.08,V = 1987.2(13)3,Z = 2,Dc = 1.666 g/cm3,F(000)= 1032,μ = 1.131 mm?1,R = 0.0633 and wR = 0.1293.According to the structural analysis,the Co(Ⅱ)ion adopts a slightly distorted six-coordinated octahedral geometry.One N atom of the Schiff base of each molecule was hydrogenated to form hydrogen bond with O atom.Two coterminous molecules packed in one crystal water molecule are linked by intermolecular hydrogen bonds,thus generating an infinite chain constructed by hydrogen bonds.
The title complex CoL (H2O) 32 H2O (C26H46N4O21S4Co2), where L = taurine-5-methyl-2-hydroxyisophthalaldehydes, has been synthesized and characterized by IR and X- ray diffraction analysis. The crystal of the complex belongs to the triclinic system = space group P1 with a = 11.197 (4) b = 13.309 (5) c = 14.486 5 α = 78.827 (13) β = 70.547 , Mr = 996.77, S = 1.08, V = 1987.2 (13) 3, Z = 2, Dc = 1.666 g / cm3, F (000) = 1032, μ = 1.131 mm 1 1, R = 0.0633 and wR = 0.1293 . According to the structural analysis, the Co (II) ion adopts a slightly distorted six-coordinated octahedral geometry. One N atom of the Schiff base of each molecule was hydrogenated to form hydrogen bond with O atom. Two coterminous molecules packed in one crystal water molecule are linked by intermolecular hydrogen bonds, thus generating an infinite chain constructed by hydrogen bonds.