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We put forward a new approach for the synthesis of Ag@Ag Cl plasmonic photocatalyst via a hydrothermal-deposition-photoreduction method. The cetylmethylammonium chloride(CTAC) was used alone as both a source of reactants and surfactant. The structure of the prepared photocatalyst was determined by XRD, SEM, EDX and UV-Vis spectroscoscopy. The photocatalytic properties were investigated by degradation of an organic pollutant, Rhodamine B, under visible light irradiation. The results reveal that the experimental conditions have a great effect on the morphology of Ag@Ag Cl crystals. Ag@Ag Cl crystal is cubic and the Ag@Ag Cl sample which is photoreduced for 40 min exhibits the highest photoactivity, and 80.6 % Rh B is degraded after irradiation for 2 hours using this catalyst. The high photocatalytic activity observed is attributed to the surface plasmon resonance effect of Ag nanoparticles.
We put forward a new approach for the synthesis of Ag @ Ag Cl plasmonic photocatalyst via a hydrothermal-deposition-photoreduction method. The cetylmethylammonium chloride (CTAC) was used alone as both a source of reactants and surfactant. The structure of the prepared photocatalyst was determined by XRD, SEM, EDX and UV-Vis spectroscopy. The photocatalytic properties were investigated by degradation of an organic pollutant, Rhodamine B, under visible light irradiation. The results reveal that the experimental conditions have a great effect on the morphology of Ag @ Ag Cl crystals. The Ag @ Ag Cl crystal is cubic and the Ag @ Ag Cl sample which is photoreduced for 40 min exhibits the highest photoactivity, and 80.6% Rh B is degraded after irradiation for 2 hours using this catalyst. The high photocatalytic activity was observed is attributed to the surface plasmon resonance effect of Ag nanoparticles.