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The crystal and molecular structure of [CoCl2(N4-trzCH2CH2COPh)4] @ 6H2O (trz = 1, 2, 4-triazole) has beendetermined by X-ray diffraction. It crystallizes in the monoclinic system, space group P21/c, with unit-cell pa-rameters a =0. 8039(2)nm, b = 1. 0822