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A new metal-organic framework(MOF) with the chemical formula of [Ni_(2) F_2(4,4'-Bipy)_(2)(H_(2) O)_(2)](VO_(3))_(2)·8 H_(2) O was introduced to adsorb Pb(Ⅱ) with the highest capacity.The sorbent was characterized by thermogravimetric analysis(TG