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采用直接水淬法成功制备直径５ｍｍ球状Ｚｒ６５Ａｌ７．５Ｃｕ１７．５Ｎｉ１０大块非晶态合金。Ｘ射线衍射、透射电镜检验证明样品完全为非晶态。采用Ｘ射线衍射、差示扫描热分析仪（ＤＳＣ）分析了Ｚｒ６５Ａｌ７．５Ｃｕ１７．５Ｎｉ１０非晶态合金的晶化过程，利用Ｋｉｓｓｉｎｇｅｒ方程求得Ｚｒ６５Ａｌ７．５Ｃｕ１７．５Ｎｉ１０非晶合金的晶化表观激活能。Ｘ射线衍射实验结果表明，Ｚｒ６５Ａｌ７．５Ｃｕ１７．５Ｎｉ１０非晶态合金的晶化是按下面的次序进行的，非晶态合金→体心立方晶相Ｚｒ２（Ｎｉ，Ａｌ）＋非晶相→体心立方相Ｚｒ２（Ｎｉ，Ａｌ）＋体心立方相Ｚｒ２（Ｃｕ，Ａｌ）。
The diameter of 5mm spherical Zr65Al7.5Cu17.5Ni10 bulk amorphous alloy was successfully prepared by direct water quenching. X-ray diffraction and transmission electron microscopy showed that the sample was completely amorphous. The crystallization process of Zr65Al7.5Cu17.5Ni10 amorphous alloy was analyzed by X-ray diffraction and differential scanning calorimetry (DSC). The apparent activation energy of Zr65Al7.5Cu17.5Ni10 amorphous alloy was calculated by Kissinger equation . X-ray diffraction results show that the crystallization of Zr65Al7.5Cu17.5Ni10 amorphous alloy is carried out in the following order: amorphous alloy → body-centered cubic Zr2 (Ni, Al) + amorphous phase → body core The cubic phase Zr2 (Ni, Al) + body - centered cubic Zr2 (Cu, Al).