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根据晶体结构数据提出含钼化学键的键价参数R0与钼氧化态n之间的线性相关性.建立了 B=0.037nm时 Mo-X(X:O,S,N,CI,F)键的直线方程.指出最近发表的与钼氧化态无关的 Mo—O键价参数 R0=0.18788 nm,B=0.03046 nm是线性相关函数中的一个特例.介绍了几个键价参数的应用实例.
According to the crystal structure data, a linear correlation between bond price parameter R0 and molybdenum oxide state n was proposed. The Mo (subscript x) O (X: O, S, N, CI, F) bonds at B = 0.037nm The linear equation is used to indicate that the recently published Mo-O bond parameter R0 = 0.18788 nm and B = 0.03046 nm, which have nothing to do with the oxidation state of molybdenum, are a special case of the linear correlation function.