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The oxide contents of TiO2, MnO, SrO and Fe2O3 in the body and graze layers of the Jiao-Tan-Xia (JTX) and Lao-Hu-Dong (LHD) porcelains in Southern Song Dynasty (1127-1279 A.D.) have been determined using an International Eagle-Ⅱμ-probe EDXRF spectrometer.