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研究了FeSO4浓度及pH值(4~8)对γFeOOH在(99±1)℃下相转化为αFe2O3的影响.结果表明,Fe(Ⅱ)/Fe(Ⅲ)为3%~5%及pH值为近中性时相转化时间最短.指出Fe(Ⅱ)离子对γFeOOH的促进作用为FeOH+吸附在γFeOOH表面使其溶解造成的.
The effect of FeSO4 concentration and pH value (4 ~ 8) on the phase transformation of γFeOOH into αFe2O3 phase at (99 ± 1) ℃ was studied. The results showed that the phase transformation time was the shortest when Fe (Ⅱ) / Fe (Ⅲ) was 3% ~ 5% and pH was near neutral. It is pointed out that the promotion effect of Fe (II) ion on γ-FeOOH is caused by the dissolution of FeOH + on the surface of γ-FeOOH.