论文部分内容阅读
从分子缔合的粘滞球模型出发,导出了同时含有自缔合和交叉缔合时亥氏函数的贡献,交叉缔合参数可由自缔合参数计算。常压和高压下二元缔合流体混合物汽液平衡的关联结果令人满意。
Based on the molecular associative viscous sphere model, the contributions of both the self-associative and cross-associative Hei’s functions are derived. The cross-correlation parameters can be calculated by self-association parameters. The correlation between vapor-liquid equilibrium of the binary fluid mixture at atmospheric pressure and high pressure is satisfactory.