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本文讨论了温度对化学反应方向和反应自发程度的影响,导出公式ΔS_孤=-ΔG/T和(ΔS_孤)/T=ΔH/T~2,分析了ΔS_孤与ΔG的区别与联系,并提出用统一的公式(ΔS_孤)/T=ΔH/T~2来描述反应方向和反应自发程度与温度的关系。
In this paper, the influence of temperature on the direction of chemical reaction and spontaneous reaction is discussed. The formula ΔS_sol = -ΔG / T and (ΔS_soluble) / T = ΔH / T ~ 2 are derived. It is proposed that the reaction direction and the spontaneous reaction degree with the temperature be described by the uniform formula (ΔS_solve) / T = ΔH / T ~ 2.