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采用[(Tp)Fe(CN)3]-(Tp=hydrotris(pyrazolyl)borate)与Mn(Ac)2·4H2O反应,合成了氰根桥联的异金属三核配合物[Mn(phen)2][(Tp)Fe(CN)3]2·5H2O(1)(phen=1,10-phenanthroline),并对其结构和磁性进行了研究。晶体结构分析结果表明该化合物晶体属于三斜晶系,P1空间群。在该配合物中,Mn!与2个phen分子及2个[(Tp)Fe(CN)3]-配位,形成一种弯曲的三核结构。磁性测量结果表明,Mn!和Fe“之间通过氰根桥联产生弱的反铁磁相互作用。
The cyanide-bridged heterometallic trinuclear complex [Mn (phen) 2] was synthesized by the reaction of [(Tp) Fe (CN) 3] - (Tp = hydrotris (pyrazolyl) borate) ] [(Tp) Fe (CN) 3] 2 · 5H2O (1) (phen = 1,10-phenanthroline) was synthesized and its structure and magnetic properties were studied. The crystal structure analysis results show that the crystal belongs to the triclinic system, P1 space group. In this complex, Mn! Coordinates with two phen molecules and two [(Tp) Fe (CN) 3] - to form a curved trinuclear structure. Magnetic measurements show that weak antiferromagnetic interactions occur between cyanide bridge and Mn! And Fe ”.