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本文用常规核磁共振方法研究了(苄基硫)(烃基硫)六羰基二铁(烃基为甲基、乙基)和动态核磁共振方法研究了(苄基硫)(叔丁基硫)六羰基二铁的异构化反应动力学,提出了可能的反应机理,讨论了影响反应速率的因素.
In this paper, we studied the synthesis of (benzylthio) (tert-butylthio) hexacarbonyl (benzylthio) (hydrocarbylthio) hexacarbonyldiiron (hydrocarbylthio and methyl) using conventional nuclear magnetic resonance and dynamic nuclear magnetic resonance Iron isomerization reaction kinetics, proposed a possible reaction mechanism, discusses the factors that affect the reaction rate.