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合成了螺旋配合物C38H29AgF6N6O0.5P并进行了元素分析、红外光谱表征和单晶X射线衍射分析。配合物为单螺旋结构,Ag(I)原子呈现扭曲的四方锥配位构型。晶体中螺旋体芳环间存在的π…π和C-H…π作用使其形成具有一维通道的三维网状结构,通道内填充有PF6-离子和结晶水分子。该晶体属于单斜晶系Cc空间群,晶胞参数分别为:a=1.7823(7)nm,b=3.1382(14)nm,c=0.8407(4)nm,β=116.492(9)°,V=4.209(3)nm3,Z=4,Mr=830.51,dc=1.311 g.cm3,T=293(2)K,μ=0.577 mm-1,F(000)=1676,R1=0.0766,wR2=0.1731[I>2σ(I)].
The helical complex C38H29AgF6N6O0.5P was synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The complex is a single helical structure, and the Ag (I) atom presents a distorted tetragonal pyramid configuration. The π ... and C-H ... π existing in the aromatic rings of the spiropy of the crystal form a three-dimensional network structure with one-dimensional channels filled with PF6- ions and crystal water molecules. The crystal belongs to the monoclinic Cc space group with unit cell parameters of a = 1.7823 (7) nm, b = 3.1382 (14) nm, c = 0.8407 (4) nm and β = 116.492 = 4.209 (3) nm3, Z = 4, Mr = 830.51, dc = 1.311 g.cm3, T = 293 (2) K, μ = 0.577 mm- 1, F (000) = 1676, R1 = 0.0766, wR2 = 0.1731 [I> 2σ (I)].