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研究了甘油丁酮缩合反应过程的动力学。结果表明,该反应为正向二级逆向二级的可逆反应;正反应速度远小于逆反应速度;正逆反应的活化能分别为41.36KJ/mol和54.66kJ/mol。在24℃~64℃内平衡常数为0.081~0.043。
The kinetics of glycerol butanone condensation reaction was studied. The results show that the reaction is a reversible two-stage reversible reaction; the positive reaction rate is far less than the reverse reaction rate; the activation energy of the forward and reverse reaction is 41.36KJ / mol and 54.66kJ / mol respectively. The equilibrium constant in the range of 24 ℃ ~ 64 ℃ is 0.081 ~ 0.043.