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当用直接电解法合成有机物而效率不高时,可考虑通过媒质进行间接电合成,使媒质与有机物先进行反应,然后通过电极反应使煤质再生。媒质包括金属离子的氧化还原电对、非金属离子或含氧酸根的氧化还原电对、有机胺、硫醚以及某些金属有机化合物等。美、日等已用间接法合成多种有机物并实现了工业规模的生产。我们正选一些易于工业化的课题,从基础研究入手并使之及早取代现有的某些污染严重、能耗过大的经典有机合成。
When direct electrolysis is used to synthesize organic matter and the efficiency is not high, indirect electrosynthesis through the medium can be considered, so that the medium and the organic matter react first and then the coal is regenerated by the electrode reaction. The medium includes the redox couple of metal ions, the redox couple of non-metal ions or oxyacids, organic amines, thioethers and certain metal-organic compounds. The United States, Japan and other indirect methods have been used to synthesize a variety of organic compounds and the realization of industrial-scale production. We are going to select some easily industrialized topics starting with basic research and making it possible to replace some of the existing classic organic synthesis that is both polluting and over-consuming.