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氧合过渡金属卟啉配合物是细胞色素P-450模拟体系的可能活性中间体。已分离和表征的钛(Ⅳ)、钒(Ⅳ)、钼(Ⅳ,Ⅴ)和铬(Ⅳ)等氧合过渡金属卟啉配合物,因其不是有效的氧化剂,所以不是细胞色素P-450模拟体系的可能活性中间体。氧合锰(Ⅳ)卟啉虽能氧化碳氢化合物,但至今还未能分离出。我们曾分离出并表征的氧合铬(Ⅳ)卟啉以及
Oxygenated transition metal porphyrin complexes are possible active intermediates for the cytochrome P-450 analog system. The oxygenated transition metal porphyrin complexes of titanium (IV), vanadium (IV), molybdenum (IV, V) and chromium (IV) which have been isolated and characterized are not cytochrome P-450 because they are not effective oxidizing agents Possible active intermediates for modeling systems. Oxygenated manganese (Ⅳ) Although porphyrin oxidation of hydrocarbons, but so far failed to separate. We have isolated and characterized oxygenated chromium (IV) porphyrins as well