In situ Nd isotopic measurement of natural geological materials by LA-MC-ICPMS

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Using newly determined Sm isotopic abundances for correcting the isobaric interference of 144Sm on 144Nd and the established mass bias relationship between Sm and Nd, a series of in situ Nd isotopic measurements were conducted for relatively high Nd concentrations of natural geological materials, including apatite, titanite, monazite and perovskite on a Neptune multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS), coupled to a 193 nm ArF excimer laser ablation system. The results show that Ce has no significant influence on the precision and accuracy of Nd isotopic analyses for LREE-enriched geological minerals and that our approach is efficient in obtaining reliable 143Nd/144Nd and 147Sm/144Nd ratios for those materials with Sm/Nd<1 (147Sm/144Nd<0.6). When combined with trace element and U-Pb isotope data, the in situ Nd isotopic data can provide important information on geological processes. Using newly determined Sm isotopic abundances for correcting the isobaric interference of 144 Sm on 144 Nd and the established mass bias relationship between Sm and Nd, a series of in situ Nd isotopic measurements were conducted for relatively high Nd concentrations of natural geological materials, including apatite, titanite , monazite and perovskite on a Neptune multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS), coupled to a 193 nm ArF excimer laser ablation system. The results show that Ce has no significant influence on the precision and accuracy of Nd isotopic analyzes for LREE-enriched geological minerals and that our approach is efficient in obtaining 143Nd / 144Nd and 147Sm / 144Nd ratios for those materials with Sm / Nd <1 (147Sm / 144Nd <0.6) data, the in situ Nd isotopic data can provide important information on geological processes.
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