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本文将改进的Scatchard-Hildebrand的溶液理论用于研究在环丁砜含盐溶液中,有机溶质和碱金属盐有特殊相互作用(氢键作用、电荷迁移作用)时,气液色谱保留参数的变化规律。并求得了特殊相互作用平衡常数K_0。
In this paper, the improved Scatchard-Hildebrand solution theory was used to study the variation of gas-liquid chromatographic retention parameters in the presence of a special interaction (hydrogen bonding, charge transfer) between an organic solute and an alkali metal salt in sulfolane-containing saline solution. And obtained the special interaction equilibrium constant K_0.