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The cationic polymerization of 1, 3-pentadiene was initiated by the organic azide/Et_2 AlClinitiating system in CH_2Cl_2 and n-hexane. The polymerizations were also carried out in parallelwith organic chloride/Et_2AlCl and Et_2 AlCl alone for comparison. The Et_2 AlCl- induced polymer-ization gives a low yield while the polymerization initiated by organic chloride/Et_2 AlCl producesmainly insoluble product. In contrast, the polymerization with azide/Et,AlCl has a high conver-sion and the resulting polymer having a high molecular weight is totally soluble. The SEC spectraof the polymers have clearly shown the differences between these initiating systems.
The cationic polymerization of 1, 3-pentadiene was initiated by the organic azide / Et_2 AlClinitiating system in CH_2Cl_2 and n-hexane. The polymerizations were also carried out in parallel with organic chloride / Et_2AlCl and Et_2 AlCl alone for comparison. The Et_2 AlCl-induced In contrast, the polymerization with azide / Et, AlCl has a high conver- sion and the resulting polymer having a high molecular weight is totally soluble The SEC spectra of the polymers have clearly shown the differences between these initiating systems.