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The crystal of the title compound (C 62 H 82 B 2ClGdO 7S 7 M r =1378.02) is triclinic with space group P1. a=12.532(2), b=12.774(2), c=24.580(5); α=93.389(9), β=104.640(8), γ=112.923(9)°, V=3451.4(8) 3, Z=2, D c =1 326g/cm 3. μ (Mo Kα )=1.258 mm -1 , F(000)=1426. R=0.036 , R w =0.091 for 12101 reflections with I>2σ(I) . The crystal is composed of a discrete cation 〔Gd(dmso) 7Cl〕 + and two anions 〔BPh 4〕 -. The Gd(Ⅲ) ion is coordinated by a chlorine and seven oxygen atoms from seven monodenate dimethylsulfoxides formimg a distorted square antiprism coordination polyhedron.
A = 12.532 (2), b = 12.774 (2), c = 24.580 (5) ; α (α) is the crystal structure of the title compound (C 62 H 82 B 2ClGdO 7S 7 M r = 1378.02) = 93.389 (9), β = 104.640 (8), γ = 112.923 (9) °, V = 3451.4 (8) 3, Z = 2 and D c = 1 326g / cm 3. μ (Mo Kα) = 1.258 mm -1, F (000) = 1426. R = 0.036, R w = 0.091 for 12101 reflections with I> 2σ (I). The crystal is composed of a phosphonium cation [Gd (dmso) 7Cl] + and two anions [ BPh 4] -. The Gd (Ⅲ) ion is coordinated by a chlorine and seven oxygen atoms from seven monodenate dimethylsulfoxides formimg a distorted square antiprism coordination polyhedron.