【摘 要】
:
The synergic extraction of uranyl thiocyanate with binary system of 1-phenyl-3-methy1~4-benzoylpyrazolone-5 (PMBP)and tributyl phosphate(TBP)or tetraphenylarso
【出 处】
:
Chemical Journal of Chinese Universities
论文部分内容阅读
The synergic extraction of uranyl thiocyanate with binary system of 1-phenyl-3-methy1~4-benzoylpyrazolone-5 (PMBP)and tributyl phosphate(TBP)or tetraphenylarsonium chloride [(C6H5)4AsCl] and ternary system of PMBP-TBP-(C6H5 )4AsCl was studied.There was an obvious synergic effect of uranium (VI)from thiocyanate medium in binary and ternary systems.The formation of a ternary extracted complex,(C6H5)4AsUO2.(NCS)A2 TBP,was confirmed by the slope method.A method was first proposed for the calculation of the equilibrium constant of ternary synergic reaction.
The synergic extraction of uranyl thiocyanate with binary system of 1-phenyl-3-methy1-4-benzoylpyrazolone-5 (PMBP) and tributyl phosphate (TBP) or tetraphenylarsonium chloride [(C6H5) 4AsCl] and ternary system of PMBP-TBP- C6H5) 4AsCl was studied. Here was an obvious synergic effect of uranium (VI) from thiocyanate medium in binary and ternary systems. The formation of a ternary extracted complex, (C6H5) 4AsUO2. (NCS) A2 TBP, was was by the slope method.A method was first proposed for the calculation of the equilibrium constant of ternary synergic reaction.
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