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利用水热合成法得到了一个结构新颖的砷钼酸盐[Ni(dien)_2])_2[As_6NiMo_6O_(30)]·2H_2O(1)(dien=二乙烯三胺),并用红外光谱、元素分析、热重分析和X射线单晶衍射对之进行了表征.化合物1属于单斜晶系,P2(1)/n空间群.化合物1是由[As_6NiMo_6O_(30)]~(4-)阴离子簇和[Ni(dien)_2]~(2+)配合物构成.
A novel structure of arsenomolybdate [Ni (dien) _2]) _2 [As_6NiMo_6O_ (30)] · 2H_2O (1) (dien = diethylenetriamine) was obtained by hydrothermal synthesis method and characterized by FTIR, elemental analysis , Thermogravimetric analysis and X-ray single crystal diffraction. Compound 1 belongs to the monoclinic space group P2 (1) / n. Compound 1 is composed of [As_6NiMo_6O_ (30)] ~ (4-) And [Ni (dien) _2] ~ (2+) complexes.