【摘 要】
：
In the past thirty years,transition metal catalyzed silylation of inert C–H bonds has attracted intensive attention due to the importance and wide use of organ
【机 构】
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Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and
【出 处】
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Science China(Chemistry)
论文部分内容阅读
In the past thirty years,transition metal catalyzed silylation of inert C–H bonds has attracted intensive attention due to the importance and wide use of organosilicon compounds.In this review,the silylation reactions of inert C–H bonds catalyzed by transition metal complexes of Ir,Rh,Ru,Pt,Pd,Ni,and Sc,and the strategies utilized to access the site-selective C–H silylation products have been summarized.Furthermore,the mechanisms of C–H silylation reactions have been discussed briefly.
In the past thirty years, transition metal catalyzed silylation of inert C-H bonds has attracted intensive due due to the importance and wide use of organosilicon compounds. This review, the silylation reactions of inert C-H bonds catalyzed by transition metal complexes of Ir, Rh, Ru, Pt, Pd, Ni, and Sc, and the strategies utilized to access the site-selective C-H silylation products have been summarized.Furthermore, the mechanisms of C-H silylation reactions have been discussed briefly.
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