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The copper(Ⅱ) complex [Cu(teta)N(CN)2](ClO4)·H2O(teta=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized and the crystal structure was determined by single-crystal X-ray diffraction. Crystal data: C18H38ClCuN7O5, monocl