【摘 要】
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The brittle-ductile transition is a very important phenomenon for polymer toughening. Polypropylene (PP) is often toughened by using rubbers, e.g., ethylene-pro
【机 构】
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Department of Polymer Science and Materials
【基金项目】
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This work was financially supported by the National Natural Science Foundation of China;the Special Funds for Major State Basic Research Projects of China;the Ministry of Education of China as a Key P
论文部分内容阅读
The brittle-ductile transition is a very important phenomenon for polymer toughening. Polypropylene (PP) is often toughened by using rubbers, e.g., ethylene-propylene diene monomer (EPDM) has often been used as a modifier. In this article, the toughening of PP by using a new kind of rubber, known as elastomeric nano-particle (ENP), and the brittleductile transition of PP/EPDM/ENP was studied. Compared to PP/EPDM binary blends, the brittle-ductile transition of PP/EPDM/ENP ternary blends occurred at lower EPDM contents. SEM experiment was carried out to investigate the etched and impact-fractured surfaces. ENP alone had no effect on the impact strength of PP, however, with the same EPDM content,PP/EPDM/ENP ternary blends had smaller particle size, better dispersion and smaller interparticle distance in contrary to PP/EPDM binary blends, which promoted the brittle-ductile transition to occur earlier.
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