由于过渡金属与硫所形成团簇在生命过程、超导、分子催化、生物固氮等领域有着广泛的应用背景,对它们的研究一直是一个引人注目的领域,我们采用激光溅射产生团簇的方式已经对Fe/S、Ta/S等多种过渡金属/硫体系进行了研究。本文报道的是Mn/s体系研究的结果,这为深入理解过渡金属/硫这类团簇化合物的性质提供了新的信息。 Since the clusters formed by transition metals and sulfur have a wide range of applications in the fields of life process, superconductivity, molecular catalysis, biological nitrogen fixation and so on, their research has been an attractive field. We use laser sputtering to generate clusters Has been on Fe / S, Ta / S and other transition metal / sulfur system has been studied. This paper reports the results of Mn / s system studies, which provides new information for understanding the properties of transition metal / sulfur cluster compounds.