Nb5+ doped Ca0.8Zn0.2TiO3:Pr3+ red long afterglow phosphors were synthesized by solid-state reaction methods.X-ray diffraction,photoluminescence spectroscopy and thermally stimulated spectrometry were used to investigate the effects of Nb5+ content on the crystal characteristics and luminescent properties of Ca0.8Zn0.2Ti1-xNbxO3:Pr3+ phosphors.The results showed that the addition of a small quantity ofNb5+ had negligible effect on the crystal characteristics of Ca0.8Zn0.2Ti1-xNbxO3:Pr3+,but it could change the trapping parameters (the depth oftrap,frequency factors and the concentration of trapped charges at t=0) of Ca0.8Zn0.2Ti1-xNbxO3:Pr3+ phosphors,and then led to the enhancement of red fluorescence and phosphorescence at 612 nm originating from 1 D2→3H4 transition of Pr3+.Both of the red fluorescence intensity and afterglow time reached the largest values in the sample of Ca0.8Zn0.2Ti1-xNbxO3:Pr3+ with x=0.05.The afterglow time of Ca0.8Zn0.2Ti0.95Nb0.05O3:Pr3+ phosphors lasted for over 24 min (≥1 mcd/m2) when the excited source was cut off.