Density functional study on enantioselective reduction of keto oxime ether with borane catalyzed by

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：yangguaiguai

【摘要】

：

The enantioselective reduction of keto oxime ether with borane catalyzed by oxazaborolidine is discussed by the density functional theory (DFT) method. The main

【作者】

：

LI Ming ZHENG Wenxu TIAN Anmi

【机构】

：

DepartmentofChemistry

【出处】

：

中国科学：化学英文版

【发表日期】

：

2006年4期

【关键词】

：

KETO OXIME ether oxazaborolidine ENANTIOSELECTIVE reduction DFT. keto oxime e

【基金项目】

：

This work was supported by the Key Project of Science and Technology of the Ministry of Education of China (Grant No. 104263).

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The enantioselective reduction of keto oxime ether with borane catalyzed by oxazaborolidine is discussed by the density functional theory (DFT) method. The main intermediates and transition states for this reaction are optimized completely at the B3LYP/6-

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