10-phenanthroline相关论文
以2,9-二正丁基-1,10-菲咯啉(dnbp)和碘化亚铜为原料, 在四氢呋喃溶液中反应合成了一种新型中性双核铜(Ⅰ)配合物［CuI(dnbp)］2。采用......
测量了1, 10-二氮杂菲和硝酸［二-(1, 10-二氮杂菲)合镧］甲醇溶液的单光子和双光子激发紫外荧光谱。 研究表明: 镧离子的配位对1, 10-......
为了获得高pH条件下Fenton体系的高效催化剂,选取了Fe~(2+)、Fe~(3+)、Co~(2+)、Ni~(2+)、Cu~(2+)、Zn~(2+)六种常见金属离子与邻......
以邻(间、对)苯二甲酸[o(m、p)-PA]和1,10_邻菲啰啉(phen)为配体,合成了5种Tb(Ⅲ)的三元配合物.各配合物的组成分别为:Tb_2(m-PA)_......
Synthesis and Characterization of a Proton-transfer Complex of 1,2,4,5-benzenetetracarboxylic Acid w
A proton-transfer complex of 1,2,4, 5-benzenetetracarboxylic acid ( H4 BTC ) with 1,10-phenanthroline ( phen ), [ ( H2 B......
Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes w
本文通过对荣华二采区10...
Non-isothermal Decomposition Kinetics of Complexes [ Sm(m-MBA)3 phen]2 and [ Sm(o-MOBA)3 phen] 2·2H2
本文通过对荣华二采区10...
Preparation, Characterization and Thermal Decomposition Kinetics of the Complexes [Dy(p-NBA)_3Phen]_
本文通过对荣华二采区10...
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
A promising green method in cyclization reaction.Oxidation of 3-methylcatechol in the presence of 1,
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Synthesis and Crystal Structure of a Novel Tetravanadate Modified by Chiral Racemoid Zirconium Compl
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Syntheses and Crystal Structures of Two Coordination Compounds CuLCl(H2O) and Ni(L)2 (HL = 2-Carboxy
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Synthesis, Characterization, Crystal Structure and Stability of a Ternary Cu(Ⅱ) complex with 1,10-Ph
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Preparation, Characterization and Thermal Decomposition Kinetics of the Complexes [Dy(p-NBA)_3Phen]_
The title complexes [Dy(p-NBA)_3Phen]_2·3H_2O(I) and [Dy(m-NBA)_3Phen]_2·4H_2O(Ⅱ) were synthesized, in the two molecu......
Non-isothermal kinetics of the first-stage decomposition reaction of the complex of samarium p-metho
The complex of [Sm(p-MOBA)3phen]2 (p-MOBA, p-methoxybenzoate; phen, 1,10-phenanthroline) was prepared and characterized ......
Synthesis and Characterization of a Proton-transfer Complex of 1,2,4,5-benzenetetracarboxylic Acid w
A proton-transfer complex of 1,2,4, 5-benzenetetracarboxylic acid ( H4 BTC ) with 1,10-phenanthroline ( phen ), [ ( H2 B......
Eu(Ⅲ)-Pyromellitic acid[PMA]-1,10-phenanthroline (phen) ternary luminescent complex was prepared in ethanol and water m......
Photophysical properties of a new ternary europium complex with 2-thenoyltrifluoroacetone and 5-nitr
A ligand,5-nitro-1,10-phenanthroline(phenNO2),was synthesized.Its Eu(Ⅲ) complex with 2-thenoyltrifluoroacetone(HTTA) wa......
Synthesis, characterization and DNA binding of the complexes of rare earth with phenanthroline and d
Three novel rare earth complexes, [Ln2(DCA)2(phen)2](NO3)2·6H2O (Ln(Ⅲ)=Sm(Ⅲ)(1), Er(Ⅲ)(2), Yb(Ⅲ)(3); DCA2-=demethyl......
A dinuclear dysprosium(Ⅲ)complex with benzoic acid and 1,10-phenanthroline,[Dy(BA)3phen]2(BA=benzoate,PHEN=l,10-phenant......
采用水溶液法,合成了铁配合物[Fe(C12H8N2)3](C6H6N2S2O6).4H2O,该配合物晶体属三斜晶系,P-1空间群,晶胞参数是:a=12.8789(12),b=1......
合成了[Cu(ctl)phen]NO_2·H_2O固体配合物,phen为1,10-邻菲咯啉;ctl为瓜氨酸(L-Citrulline),通过元素分析、红外光谱(IR)、紫外光......
Synthesis and Structure of Barium Complex Containing 2,2,6,6-Tetramethyl-3,5-heptanedionate and 1,10
The title complex Ba(thd)2 (phen)2 (thd = 2, 2, 6, 6-tetramethy1-2, 5-heptanedionate, phen = 1, 10-phenanthroline) (C46 ......
以2-氨基乙醇(EA)和邻菲咯啉(PHEN)为配体合成了新配合物[Co(PHEN)2(EA)](ClO4)2·H2O·CH3OH,其结构经IR,元素分析和X-射线单晶衍......
The crystal structure of the title compound {[Mn(phen)2(OAc)(H2O)]C1O4}2@H2O(phen = 1,10-phenanthroline) has been synthe......
Electrochemical Studies of Eight New Divalent Transition Metal Benzenesulphonate Ternary Complexes w
The electrochemical properties of eight new divalent transition metal benzenesulphonate complexes with 1,10-phenanthroli......
Synthesis and Crystal Structure of a New Ternary Complex of Nickel(Ⅱ) with L-Aspartic Acid and 1,10-
A new ternary complex of nickel(Ⅱ) with L-aspartate (L-Asp) and 1, 10-phenanthroline(Phen), [Ni3(L-Asp)(Phen)5(H2O)3](C......
Synthesis, Characterization, Crystal Structure and Stability of a Ternary Cu(Ⅱ) complex with 1,10-Ph
IntroductionIt is important to research the mixed-ligand copper complexes containing bioligands,such as amino acids, nuc......
Preparation and Structural Analysis of Lanthanide Complexes with α-Hydroxyl-phenyl-acetic Acid and 1
A series of ternary lanthanide complexes Ln(C6H5CHOHCOO)3(phen) (H2O) (Ln= La, Ce, Pr, Nd,Sin, Eu) were synthesized with......
A manganese coordination polymer [(phen)MnCl2]n (phen = 1,10-phenanthroline,C12H8N2) with formula C12H8Cl2MnN2 and Mr = ......
A dinuclear manganese(II) complex, [Mn2(μ-Oac)2(phen)4](ClO4)2 1 (phen = phenanthroline), has been prepared by the reac......
Synthesis and Crystal Structure of a Novel Ternary Ni(II) Complex with 2-Hydroxyl-1,10- phenanthroli
A novel ternary complex of [NiL1L2·2H2O]·NO3·H2O (L1 = 2-hydroxyl-1,10-phe- nanthroline (Hophen), L2 = 2-hydroxynicot......
Synthesis and Crystal Structure of an Ion-pair Supramolecular Associate 2,9-Diformyl- 1,10-phenanthr
2,9-Diformyl-1,10-phenanthrolinebis(2,6-dimethylanil)cobalt(Ⅱ) perchlorate was synthesized and demonstrated to be [CoL2......
Synthesis and Crystal Structure of a Novel Tetravanadate Modified by Chiral Racemoid Zirconium Compl
[Zr(phen)4(H2O)4O2(V4O12)](phen)2 1 (phen = 1,10-phenanthroline) was synthesized under hydrothermal condition. The cryst......
An operationally simple and inexpensive catalyst system was developed for the cross coupling of potassium thiocyanate wi......
A new mononuclear copper(Ⅱ) complex [CuL(Phen)]·NO3 (L = 2-{2-[(3,5-dibro- mosalicylidene)amino]ethyl}-1H-1,3-benzimid......
Syntheses and Crystal Structures of Two Coordination Compounds CuLCl(H2O) and Ni(L)2 (HL = 2-Carboxy
Two complexes CuLCl(H2O) 1 and Ni(L)2 2 (HL = 2-carboxy-1,10-phenanthroline) have been synthesized and characterized by ......
Trinuclear and Dinuclear Manganese Complexes of 2/4-Formylbenzoic Acid Oxime Ligands:Syntheses and C
Two manganese complexes, [Mn3(2-cba)6(phen)2] 1 (2-cba = 2-cyanobenzoic acid, phen = 1,10-phenanthroline) and [Mn2(4-fba......
A promising green method in cyclization reaction.Oxidation of 3-methylcatechol in the presence of 1,
Electrochemical oxidation of 3-methylcatechol as a model compound has been studied in the presence of 1,10-phenanthrolin......
Thermal Stability and Luminescence Properties of Eu3+ and Tb3+ Complexes with a Silica Matrix by Sol
Ternary complexes of europium and terbium with benzoic acid and 1, 10-phenanthroline [RE(BA)3phen] (BA=benzoate phen=1,1......
The stability constants of binary complexes Ln-L (Ln=La3+, Ce3+, Pr3+, Nd3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Ho3+, L=N, N......
本文以稀土铕、钐(Eu、Sm)氯化物、呋喃甲酸(L)和1,10-邻菲啰啉(phen)为原料,95%乙醇为溶剂,合成了两种新型的稀土配合物([Eu(L)3 ......
用密度泛函(DFT)法,对配合物[Ru(phen)2(6,6'-2R-dpq)]2+(R=F,H,OH)进行了理论计算研究.探讨了配合物的电子结构与其抗癌活性......
通过试验认为盐酸胍的存在对邻菲罗啉亚铁吸收曲线、吸光值稳定的pH范围、显色剂用量及有色物的稳定性等均无影响,并建立了邻菲罗......
利用2-氟异烟酸为配体合成并表征了一例稀土铕离子配位聚合物{[Eu（L）2（phen）（OH）]}n（1）（HL=2-氟异烟酸,phen=1,10-邻菲罗啉）,是一个由2-氟异......
研究了以1,10-邻菲罗啉为原料,经氧化和氯代反应合成2-氯-1,10-邻菲罗啉,再经氨基化反应得到目标产物2-氨基-1,10-邻菲罗啉,化合物......
以邻苯二胺和乙氧亚甲基丙二酸二乙酯为起始原料，经取代、环合、水解、脱羧等反应合成得到4，7-二羟基邻菲罗啉，4，7-二羟基邻菲罗啉进一......
邻二氮菲分光光度法测定黄芪中铁的溶出率,研究了不同溶剂对铁的溶出率的影响。检测波长510nm,在0.1—6μg·mL^-1的范围内符......
以1,10-邻菲咯啉和硫酸锌合成了新型的硫酸配合物[2ZnSO4(Phen)2H2O]⋅3CH3OH⋅H2O,并用X-射线衍射分析对其结构进行了表征。结果......
