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用高分子材料负载季鏻盐相转移催化剂的开发和研究已有报导。Reeves和Idoux曾用氯甲基聚苯乙烯树脂经多步反应制得催化剂。Tomoi通过CF_3SO_3H催化ω-溴代烯烃与树脂付-克烷基化反应制得溴烃基树脂,再与三烃基膦反应制成高分子负载季磷盐催
The development and research of quaternary phosphonium salt phase transfer catalysts supported by polymer materials have been reported. Reeves and Idoux have chloromethyl polystyrene resin obtained by a multi-step reaction catalyst. Tomoi catalyzed the co-bromination of ω-bromo-alkenes with resins by CF_3SO_3H to obtain brominated hydrocarbon-based resins and then reacted with trialkylphosphine to form the polymer-supported quaternary phosphonium salts