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山东易达利化工有限公司自主开发了碳四氧化和加氢生产甲基烯丙醇环境友好新工艺。该工艺以叔丁醇(或异丁烯)为原料经过氧化和加氢生产甲基烯丙醇,工艺路线主要有两个步骤,第一步是叔丁醇氧化合成甲基丙烯醛;第二步是甲基丙烯醛加氢合成甲基烯丙醇,原子利用率为80%。在开发过程中,先后解决了加氢选择性差、甲基丙烯醛防聚合
Shandong Yida Dali Chemical Co., Ltd. independently developed carbon tetraoxide and hydrogenation of methyl allyl alcohol environment-friendly new technology. The process uses t-butanol (or isobutylene) as raw material to produce methallyl alcohol through oxidation and hydrogenation. The process includes two steps: the first step is the oxidation of tert-butanol to methacrolein; the second step is Methacrolein hydrogenation of methyl allyl alcohol, atomic utilization was 80%. In the development process, has solved the poor selectivity of hydrogenation, methacrolein anti-polymerization