【摘 要】
：
A series of RbxCs1-xAg4I5 (x = 0-1) thin films were grown by vacuum evaporation on NaCl crystal substratesat 350K. The absorption spectra of these films were me
【机 构】
：
Key Laboratory of Atomic and Molecular Nanosciences of Education Ministry and Department of Physics,
论文部分内容阅读
A series of RbxCs1-xAg4I5 (x = 0-1) thin films were grown by vacuum evaporation on NaCl crystal substratesat 350K. The absorption spectra of these films were measured at 80 K in the wavelength range from 240nm to 400nm. It is shown that superionic conductor thin films of quateary compound Rb0.5Cs0.5Ag4I5 and tearycompound RbAg4I5 can be obtained at x = 0.5-0.6 and x = 0.7-1, respectively. At x = 0.65, the combinedcompound film of the mixture of 30mol% RbAg4I5 and 70mol% Rb0.5Cs0.5Ag4I5 is presented. Then, based on the spectral positions of the A1 and A2 peaks, we determined that the Rb0.5Cs0.5Ag4I5 exciton coupling energy Rex is 0.21 eV, the forbidden zone width Eg is 3.82eV and the exciton radius aex is 0.70nm. Furthermore, the ionic conductivities of superionic conductor thin films of RbAg4I5 and Rb0.5Cso.5Ag4I5 and their mixture film are investigated, respectively, in the temperature range 303 K-393 K.
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