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用分光光度法研究了四磺酸基酞菁钒(Ⅳ)(VOTsPc)在溶液中的二聚反应,报道了二聚常数及其与温度、溶剂组成的关系,计算了不同温度下二聚反应的部分热力学数据,同时对水分子在二聚反应中的作用进行了讨论。
The dimerization of tetrasulfonate vanadyl (IV) phthalocyanine (IV) (VOTsPc) in solution was studied by spectrophotometry. The dimerization constants and their relationship with temperature and solvent composition were reported. The dimerization reaction Part of the thermodynamic data, at the same time, the role of water molecules in the dimerization reaction are discussed.