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以六氟异丙醇(HFIP)为溶剂,采用静电纺丝技术制备丝素(SF)-聚己内酯(PCL)复合纳米纤维膜。采用热场发射扫描电镜、Image-Pro Plus图像分析和力学拉伸的方法表征了纳米纤维膜的结构与力学性能。通过设计的三因素四水平正交试验对复合纳米纤维膜的多个指标进行了分析,采取归一化数据处理及平均权重分配的方式量化了复合纳米纤维膜的品质,确定了共混复合纳米纤维膜制备的最优工艺参数,并且采用最佳工艺参数制备了SF-PCL复合纳米纤维膜,分析了其力学性能。结果表明:在溶质质量分数为6%、溶质SF与PCL质量比为3∶2、纺丝流速1.2 mL/h时,SF-PCL复合纳米纤维膜具有较好的品质;双轴拉伸时的破坏机制与单轴不同,其断裂应力和应变只是单轴时的一半左右,膜的力学性能表现为各向同性。
Silk fibroin (SF) - polycaprolactone (PCL) composite nanofibers were prepared by electrospinning using hexafluoroisopropanol (HFIP) as solvent. The structure and mechanical properties of nanofiber membranes were characterized by thermal field emission scanning electron microscopy, Image-Pro Plus image analysis and mechanical stretching. Through the design of three-factor and four-level orthogonal experiment, the multiple indicators of the composite nanofiber membrane were analyzed. The quality of the composite nanofiber membrane was quantified by normalized data processing and weighted average weight distribution. SF-PCL composite nanofiber membrane was prepared by using the best technological parameters, and its mechanical properties were analyzed. The results show that SF-PCL nanofibers have better quality when the mass fraction of solute is 6%, the mass ratio of solute SF to PCL is 3: 2 and the spinning flow rate is 1.2 mL / h. When biaxial stretching The failure mechanism is different from that of uniaxial. The fracture stress and strain are only about half of those at uniaxial moment. The mechanical properties of the film are isotropic.