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合成了新的含硫希夫碱配体对氨基苯乙酮双缩硫代对称二氨基脲 ,在以此化合物为配体的非水溶剂中 ,用 Cu,Zn,Fe,Sn,Pb金属做阳极 ,首次用电化学金属阳极氧化法合成了对氨基苯乙酮双缩硫代对称二氨基脲 (HL)与 Cu( ) ,Zn( ) ,Fe( ) ,Sn( ) ,Pb( )的金属配合物 ,通过元素分析、红外光谱、紫外光谱、磁化率、摩尔电导率等对配体和配合物进行了结构表征 .
Synthesis of a new sulfur-containing Schiff base ligand p-aminoacetophenone bis-substituted thio-symmetric two semicarbazide, in this compound as a ligand in a non-aqueous solvent, with Cu, Zn, Fe, Sn, Pb metal do Anodes were synthesized by the electrochemical oxidation of metal for the first time. Metal complexes of p-aminoacetophenone double-condensed thio-symmetric diaminourea (HL) with Cu (), Zn The complexes were characterized by elemental analysis, IR, UV, magnetic susceptibility, molar conductivity and so on.