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Two novel interpenetrating diamond frameworks,namely [Cd(mal)(bix)]n(1) and {[Zn(sub)(bib)]n·H2O}n(2)(H2mal=maleic acid,H2 sub=suberic acid,bix=1,4-bis(imidazol-1-ylmethyl)-benzene,bib=1,4-bis(N-imidazolyl)butane) were hydrothermally synthesized and