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慕尼黑酮是一种介离子型五元杂环化合物,在杂环化学乃至有机化学中占有着重要地位.自从1964年Huisgen发现并命名这类化合物以来,其合成、性质和应用的研究吸引了越来越多的兴趣.它的重要性质之一是可以作为1,3-偶极体与不饱和键发生环加成反应,该反应现已成为合成吡咯及其它一些杂环化合物的一种重要方法.近年来,人们开始通过金属有机反应来实现慕尼黑酮的合成,慕尼黑酮新的反应性质得到进一步探索,慕尼黑酮在有机合成上的应用也越来越普遍.对慕尼黑酮研究最新进展进行了总结.
Munchenone is a meso-ionic five-membered heterocyclic compound that plays an important role in heterocyclic chemistry and even in organic chemistry. Since its discovery and naming in 1964, Huisgen has attracted more and more attention on its synthesis, properties and applications One of its important properties is that it can act as a cycloaddition reaction of 1,3-dipole with an unsaturated bond and this reaction has now become an important method for the synthesis of pyrrole and some other heterocyclic compounds In recent years, people began to realize the synthesis of the ketone by means of metal - organic reaction, and the new reaction properties of the mannone ketone were further explored, and the application of the mannone ketone in the organic synthesis became more and more common. .