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介绍了一系列含μ-CO配体的蝶状Fe/E(E=S,Se,Te)簇盐的化学研究进展.这些簇盐包括11种新颖簇阴离子,它们是单蝶状单μ-CO阴离子[(μ-RE)(μ-CO)Fe2(CO)6]-(A,E=S,Se,Te),双蝶状双μ-CO阴离子{[(μ-CO)Fe2(CO)6]2(μ-EZE-μ)}2-(B,E=S;C,E=Se),三蝶状三μ-CO阴离子{[(μ-CO)Fe2(CO)6]3[(μ-SCH2CH2)3-N]}3-(D),{[(μ-CO)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3-(E),{[(μ-CO)Fe2(CO)6]3[(μ-SCH2)3CMe]}3-(F)及由F转化的双蝶状单μ-CO阴离子{[(μ-CO)Fe2(CO)6][Fe2-(CO)6][(μ-SCH2)3CMe]}-(G),四蝶状四μ-CO阴离子{[(μ-CO)Fe2(CO)6]4[1,2,4,5-(μ-SCH2)4C6H2]}4-(H)及由它转化的三蝶状双μ-CO阴离子{[(μ-CO)Fe2(CO)6]2[Fe2-(CO)6][1,2,4,5-(μ-SCH2)4C6H2]}2-(I),四蝶状四μ-CO阴离子{[(μ-CO)Fe2(CO)6]4[(μ-SCH2)4C]}4-(J)及由它转化的三蝶状双μ-CO阴离子{[(μ-CO)Fe2(CO)6]2[Fe2(CO)6]-[(μ-SCH2)4C]}2-(K).文中不仅描述了这十一种阴离子簇盐的形成方法,而且阐述了它们所发生的新颖反应以及由这些反应所生成的多种新型蝶状Fe/E簇合物,具有重要理论和应用价值.
A series of chemical studies on the cluster-like Fe / E (E = S, Se, Te) cluster salts containing μ-CO ligands are presented. These cluster salts include 11 novel cluster anions, CO anion [(μ-CO) Fe2 (CO) 6] - (A, E = S, Se, Te) (Μ-EZE-μ)} 2- (B, E = S; C, E = Se) [(μ-SCH2CH2) 3-N]} 3- (D), {[(μ-CO) Fe2 (CO) 6] 3 [1,3,5- ), [(μ-CO) Fe2 (CO) 6] 3 [(μ-SCH2) 3CMe]} 3- (Μ-CO) Fe2 (CO) 6] 4 [Fe2 (CO) 6] [(μ-SCH2) 3CMe]} - [Μ-CO 2 Fe 2 (CO) 6] 2 [1,2,4,5- (μ-SCH2) 4C6H2]} 4- Fe (CO) 6] [1,2,4,5- (μ-SCH2) 4C6H2]} 2- (I) (Μ-CO) Fe2 (CO) 6] 2 [Fe2 (CO) 6] 4 [(μ-SCH2) 4C]} 4- - [(μ-SCH2) 4C]} 2- (K) .In this paper, we not only describe the formation methods of these eleven anionic cluster salts, but also describe their novel reactions and their reactions A variety of new butterfly Fe / E clusters, has important theoretical and practical value.