自从联吡啶钌光催化分解水的能力被人们认识以来,围绕Ru(bpy)_3~(2+)深入研究了这类具有光敏性配合物及其衍生物的合成,化学反应性,氧化还原性,激发态的反应性,光诱导分子内和分子间电子转移和能最传递过程以及光化学取代反应等光化学和光物理过程。二茂铁及其衍生物作为一类经典的金属有机化合物从其产生到现在一直是配位结构化学和无机光化学研究的重要对象。其对Ru(bpy)_3~(2+)等光敏剂的猝灭作用引起人们的广泛重视。 Since the ability of ruthenium biphthalate photocatalytic decomposition of water has been recognized, the synthesis, chemical reactivity, redox activity of these photoactive complexes and their derivatives have been thoroughly studied around Ru (bpy) _3 ~ (2+) , Excited state reactivity, light-induced intramolecular and intermolecular electron transfer and the most transfer process and photochemical substitution reactions and other photochemical and photophysical processes. Ferrocene and its derivatives as a class of classic metal organic compounds from its generation to now has been an important object of coordination structure chemistry and inorganic photochemistry. Its quenching effect on photosensitizers such as Ru (bpy) _3 ~ (2+) has drawn people’s attention.