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1959年西德J,Smidt报导了由烯烃直接氧化合成羰基化合物的新方法;1960年И.И.Моисеев报导了乙烯直接合成醋酸乙烯的新方法。他们都采用了钯盐催化剂。新方法引起普遍重视,主要是由于在原料上乙烯和乙炔之间的竞争(前者主要来自石油,且价廉,后者主要来自煤,电耗大,成本高),促进了对钯系催化剂的研究。从六十年代初期到现在,用钯系催化剂进行烯烃的氧化反应,已成功用于工业生产乙醛、丙酮、醋酸乙烯等化工原料。关于催化氧化过程的热力学、动力学、机理等有关反应实质的研究,和钯系催化剂作用下的新的烯烃的氧化反应及扩展应用的研究,
In 1959 West Germany, Smidt reported a new method for the direct synthesis of carbonyl compounds from olefins. In 1960, the new method for the direct synthesis of vinyl acetate from ethylene was reported by И.И.Моисеев. They all use palladium salt catalysts. The new method has attracted widespread attention, mainly due to the competition between ethylene and acetylene on the feedstock (the former is mainly from petroleum and is inexpensive, the latter is mainly from coal, the power consumption is high, the cost is high), and the promotion of the palladium-based catalyst the study. From the early 1960s to the present, the oxidation of olefins with palladium-based catalysts has been successfully used in the industrial production of acetaldehyde, acetone, vinyl acetate and other chemical raw materials. On the catalytic oxidation process of thermodynamics, kinetics, mechanism and other related to the substance of the research, and palladium catalyst under the action of the new olefin oxidation and expansion of the application of research,