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合成和表征了４种以四溴代邻苯二甲酸根阴离子（４Ｂｒ－ＰＨＴＨ）桥联、以１，１０－菲咯啉（ｐｈｅｎ），５－硝基－１，１０－菲咯啉（ＮＯ_２－ｐｈｅｎ），２，２′－联吡啶（ｂｐｙ）和４，４′－二甲基－２，２′－联吡啶（Ｍｅ_２ｂｐｙ）端接的双核钴（Ⅱ）配合物［Ｃｏ_２（４Ｂｒ－ＰＨＴＨ）（Ｌ）_４］（ＣｌＯ_４）（Ｌ＝ｐｈｅｎ（ｌ），ＮＯ_２－ｐｈｅｎ（２），ｂｐｙ（３），Ｍｅ_２ｂｐｙ（４））。基于ＩＲ光谱、元素分析、电导测量等方法推定配合物具有四溴代邻苯二甲酸根桥联结构和Ｃｏ（Ⅱ）离子具有畸变的八面体配位环境。进行了配合物变温磁化率（７５～３００Ｋ）的测定，其数据已用从自旋哈密顿符导出的磁方程拟合，求得交换参数Ｊ＝－０．８７ｃｍ~（－１）（１），－０．８４ｃｍ~（－１）（２），－０．８２ｃｍ~（－１）（３），－０．８５ｃｍ~（－１）（４），表明金属离子间有弱的反铁磁性自旋交换相互作用。
Four kinds of tetrabutyl phthalate anion (4Br-PHTH) bridged with 1,10-phenanthroline (phen), 5-nitro-1,10-phenanthroline -phen), 2,2’-dipyridyl (bpy) and 4,4’-dimethyl-2,2’-bipyridine (Me_2bpy) (L) _4] (ClO_4) (L = phen (l), NO_2-phen (2), bpy (3), Me_2bpy (4)). Based on the IR spectra, elemental analysis and conductometric measurements, the complex was assumed to have a tetrabromophthalic anhydride bridge and a distorted octahedron coordination environment for Co (Ⅱ) ions. The magnetic susceptibility (75 ~ 300K) of the complex was measured. The data were fitted by the magnetic equation derived from spin Hamiltonian, and the exchange parameter J = -0.87cm -1 was obtained (1) , -0.84cm -1, -2.82cm -1, -3.8cm -1, respectively, indicating weak antiferromagnetic properties between metal ions Spin exchange interaction.