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使用α-甲基吡啶与足量硫磺和苯胺共热,产物真空分离,乙醇中重结晶,制备?C_(12)H_3N_2S(Ⅰ),C_(13)H_(11)N_2S(Ⅱ)和C_(13)H_(10)N_2S(Ⅲ),利用单晶x-射线衍射,?空??个同系物的晶体和分子结构。
The reaction of α - picoline with sufficient sulfur and aniline was carried out. The product was separated by vacuum and recrystallized from ethanol to prepare (C) (12) H_3N_2S (Ⅰ), C_ (13) H_ 13) H_ (10) N_2S (Ⅲ), crystal and molecular structure of a homologue by single crystal x-ray diffraction.