Measurement of the association constants through micro-Raman spectra of supersaturated lithium perc

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有 nanogram 规模的质量的 LiClO4 微滴的高质量的 micro-Raman 系列在各种各样的集中被获得从冲淡到使过饱和的状态。从 v 1-ClO4 乐队的部件乐队分析,在 933.3, 936.8, 942.1 和 950.7 cm1 的四座山峰被识别并且分别地分到免费 solvated 高氯酸盐阴离子,分享溶剂的离子对,接触离子对和复杂离子总数。是期望,免费 solvated ClO4 离子的签名被观察随集中的增加在紧张减少。当集中进一步被增加到 5.6 mol/kg,从分享溶剂的离子对的
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