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Anodic oxidation of Co, Cu, Zn, and Sn metals in an acetone solution of 1,1-malonayl-bis(4-p- Chlorophenylthiosemicarbazide) yields complexes of composition with general formula [Co2(pClMaTS)(H2O)6]·2H2O, [Cu2(pClMaTS)(H2O)6], [Zn2(pClMaTS)(H2O)6] an