COMPLEXES相关论文
Intramolecular hydrogen bonding interaction,a mechanism for the bridging linkages to exert electroni
Seven diiron hexacarbonyl complexes,[Fe_2(L)(CO)_6](L = two monothiolate or dithiolate ligans),as the mimics of the diir......
Based on fieldwork and specimen examination,taxonomic revision of Dendrobium moniliforme complex and Dendrobium scoriaru......
报道了具有良好电荷转移特性的Ru络合物,采用四波混频方法对其非线性光学性能进行了测量,由此推算出三阶非线性光学极化率和分子的......
Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ),
...
The rapid generation of molecular in a relatively easy manner has made the cycloaddition reaction a powerful tool in the......
The reaction of CdCl2 with 6,7-dicyanodipyridoquinoxaline (DICNQ) by solvothermal reaction gives rise to a coordination ......
A combination of molecular dynamics (MD) and density functional theory (DFT) calculations were used to study the hydrati......
The molecular geometry,electronic structure,thermochemistry and infrared spectra of [Mg(CHZ)3](ClO4)2 and [Mg(CHZ)3](NO3......
A novel zinc(Ⅱ) complex, Zn(IBT) 2 (1, HIBT=5-(4-((1H-imidazol-1-yl)methyl)phenyl)-2H-tetrazole) has been synthesized w......
Eu(OA)3(TTA) (OA=cis-9-octadecenoic acid, TTA=4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione) complexes (Eu- complexes) c......
S-doped and Al-doped GaSe crystals are promising materials for their applications in nonlinear frequency conversion devi......
Speciation of Pr(III) in human blood plasma has been investigated by computer simulation. The speciation and distributio......
Heteropoly-complexes K17[Ln(CuW11O39)2].xH2O(Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Dy) were prepared. The properties of the ......
As the catalysts for carbonylation of methanol to acetic acid, the homogeneous complexes are
As the catalysts for carb......
The insecticide cartap(CP) is non-fluorescent in aqueous solutions.This property makes its determination through direct ......
The Copper(Ⅰ) supramolecular complexes of 4,5-bis(methylthio)-1,3-dithiole-2-thione (C5H6S5), [Cu(C5H6S5)(SCN)]∞ 1 and......
A new complex [Zn(OH2)(HDPA)2]·3H2O 1 (H2DPA = 2,6-pyridine-dicarboxylic acid) has been prepared at room temperature fr......
Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6-12H2O (1), [Co(bpm......
The polymerization of alkyl isocyanates catalyzed by rare earth chloride salen complexes/triisobutyl aluminum(Ln(H2salen......
A series of Eu(Ⅲ) complexes of α-thenoyltrifluoroacetone(HTTA) with trioctylphosphine oxide(TPPO) and benzoic acid(BA)......
The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following organiz......
Supramolecular medicinal chemistry field has been a quite rapidly developing,increasingly active and newly rising interd......
Four bismuth complexes, (H2En)[Bi2(cit)2(H2O)4/3]·(H2O)x (1), (H2En)3[Bi2(cit)2Cl4]·(H2O)x (2), (HPy)2[Bi2(cit)2(H2O)8......
Cucurbit[n]urils (Q[n]) are promising ligands for the coordination of metal ions, metal complexes or clusters, and form ......
Donald J. Cram, the great UCLA chemist, received the No-bel Prize for his discoveries about host-guest complexes [1]. Bo......
利用电喷雾质谱(ESI-MS)和紫外-可见吸收光谱(UV-Vis)分析,研究了CrCl3·6H2O 浓度为0.1~0.6 mol·L -1的水溶液和[1ChCl:2EG]/CrC......
Two Carboxylato-bridged Binuclear Cobalt(Ⅱ) Complexes Pillared Coligands: Synthesis,Structures and M
By adopting mixed-ligand strategy,two Co(Ⅱ) coordination polymers,[Co(phda)(itmb)(H2O)2]n (1) and[Co(phda)(Hpytz)]n (2)......
Impact of polydimethylsiloxanes on physicochemical and tribological properties of naphthenic mineral
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生......
通过1-n-丁基-3-甲基咪唑六氟磷酸盐离子液体([BMIM][PF6])/环己烷构建了液/液两相体系。研究了两相体系内反应温度、Al/Cr摩尔比......
Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1,2-dichalcogenolate c
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
In this study, X-ray diffraction (XRD), Fourier transform infrared spectrometer (FTIR) together with Scanning probe micr......
The binary complexes of terbium with benzoic acid and its derivatives (phthalic acid,iso-phthalic acid,oaminobenzoic aci......
Synthesis, Characterization and Fluorescence of Terbium(Ⅲ) Complexes with Phenylglyoxylic Acid and 2
Three new complexes TbL3dipy(H2O)2, TbL3phen(H2O)2 and TbL2(TPPO)2NO3 were synthesized (L=phenylglyoxylate ion, dipy=2,2......
Synthesis and co-luminescence properties of Tb3+-methacrylic acid-1,10-phenanthroline complexes dope
A series of rare earth complexes Tb1-xEux(MAA)3phen (x=0.00,0.01,0,03,0.05,0.07,0.09,0.10,0.30,and 0.50) were synthesize......
The systems containing EHPG, EHPG-OCH3 and EHPG-NH-Ac and Tb(Ⅲ) ions were used to study chemiluminescence (CL) and elec......
Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1,2-dichalcogenolate c
The reactions of [CptRhCl((-Cl)]2 (1) (Cpt = tBu2C5H3) with Li2E2C2B10H10 (E = S, Se) lead to the green 16-electron dich......
Syntheses and Structural Researches of Nine-coordinate K3[TbIII(nta)2(H2O)] 5.5H2O and Eight-coordin
The crystal and molecular structures of K3[TbIII(nta)2(H2O)](5.5H2O (nta = nitrilotriacetic acid) and K3[YbIII(nta)2](5H......
Synthesis, Characterization and Luminescent Properties of Complexes of Rare Earth Nitrates with 2,2′
The rare earth nitrate complexes with 2,2′:4′,4″:2″,2-quaterpyridine (L) were prepared in ethylacetate. These new ......
Influence of La, Y, Gd, Cu, NH4+ Ions and DMSO on Luminescent Property of Terbium Complexes with Sul
The complex Tb(SSA)*H2O (1) and Tb2.5La (SSA)3.5*7H2O (2), TbY(SSA)2*2H2O (3), Tb1.5Gd(SSA)2.5*4H2O (4), TbGd1.5(SSA)2.5......
以罗丹明B酰肼为主体,利用马来酸酐、4-氨基苯甲醛为原料修饰主体设计合成一种功能性发光小分子配体(MRBHP)。MRBHP在乙腈与水溶液......
利用高效液相色谱仪(HPLC)分析并比较了两种溶剂溶解的中药水提物样品中大黄素的含量,对中药水提物中大黄素-金属配合物的存在进行......
合成了6个新的烯唑醇配合物,通过元素分析、IR光谱和X-射线单晶衍射表征了配合物的结构。结构分析表明：1属三斜晶系,空间群P-1,晶胞......
近日,我校化学化工学院教师张付力博士在高性能有机电致发光染料研究领域取得了重要进展.其所著论文《Highly efficient green pho......
合成了两种吲哚醌类Schiff碱配体及其过渡金属Cu（Ⅱ）、Zn（Ⅱ）、Mn（Ⅱ）、Co（Ⅱ）、Ni（Ⅱ）的配合物,并用电子光谱、红外光谱、1H NMR加以表征。......
合成了D-（＋）-葡萄糖缩氨基硫脲合钼、铬金属配合物。对化合物进行了元素分析、IR等测试。并对化合物与DNA作用的电子吸收光谱进行了研......
自从1965年B.Rosenberg等发现顺式-二氯二氨合铂(Ⅱ)能抑制大肠杆菌的细胞分裂、在1969年发现它的抗动物肿瘤活性后,在探索新的有......
作为目前国际上常用的铀的萃取剂,磷酸三丁酯(TBP)对铀有较强的萃取能力,但其耐辐射能力较差,于是人们开始寻找TBP的替代品[1～4].酰......
用精密pH电位法测定了在甲醇-水混合溶剂中配体氨三乙氧基三苯甲酸(NEB)质子化常数(25℃,I=0.20mol*L-1 NaCl),讨论了溶剂对质子化......
铜是生物体内必需的微量元素，是一些重要酶的活性中心，其配合物不仅在生命体系有着特殊的生物活性，而且由于具有特殊的磁学、电学、光......
